Synthesis, Characterization and In vitro Antitumour Activity of Novel Organotin Derivatives of 1,2- and 1,7-Dicarba-Closo-dodecaboranes
نویسندگان
چکیده
Several organotin derivatives of 1,2- and 1,7-dicarba-closo-dodecaboranes were synthesized and characterized by (119)Sn Mössbauer, (1)H, (13)C and (119)Sn NMR spectroscopy. Their antitumour activities in vitro against cancerous cell lines of human origin are reported.
منابع مشابه
Some Recent Advances in the Chemistry of Dicarba-clos O-dodeca- Boranes(12), B1 0h1 0c 2rr'
Experimental data on the mutual rearrangements of isomeric dicarba-closododecaboranes(12) and their B-halogen derivatives are reviewed. Reactions involving electron transfer to dicarba-closo-dodecaboranes(12), and the properties of the resulting dodecahydrodicarba-nido-dodecaborates(2 —) as intermediates of the rearrangements of 1.7and 1,12-dicarba-closo-dodecaboranes(12) are discussed. Attenti...
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Electrophilic iodination of the 7,9-dicarba-nido-undecaborate anion with molecular iodine in the presence of AlCl3 generated a new carborane anion-8-iodo-7,9-dicarba-nido-undecaborate-in excellent yield. The capping of the new anion with HBCl2 yielded a previously unknown neutral iodinated carborane, 2-iodo-1,7-dicarba-closo-dodecaborane.
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ورودعنوان ژورنال:
- Metal-Based Drugs
دوره 2 شماره
صفحات -
تاریخ انتشار 1995